How To Style 2 Different Links Properly

I am playing around with a real basic website that I am using as a learning tool and I am trying to figure out the proper way to style two completely different links.

For one link it is styled as follow:

.
#toppics {
    clear:both; /* make sure this is past both columns */
    padding:2em 0 1em;
    margin:0 2em;
    border-top:2px solid #400;
}

#toppics ul {
    list-style:none;
    padding-bottom:1em;
}

#toppics li {
    display:inline;
    vertical-align:top;
}

#toppics a {...
Code (markup):
How To Style 2 Different Links Properly

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