Msmtp-problem - multiple virtual hosts, all using default

I have set up msmtp as a way to send emails - however, I can't seem to get it to pick the right config for sending emails from different vhosts, and I'm getting nowhere with googling.

I'm using Google servers, btw, if that matters - that works, not problem, it's just that it picks the default account, instead of the specific account

What I have is this:
(/etc/.msmtp_php - conf-file)

defaults
host smtp.gmail.com
port 587
auth on
tls on
tls_certcheck off
syslog LOG_MAIL

#account for...
Code (markup):
Msmtp-problem - multiple virtual hosts, all using default

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